Title: The 10 Best 5 Star Hotels in Val d'Orcia - 2025 Updated Prices | Expedia.co.uk [Val d'Orcia Travel Guide](https://expedia.co.uk/Val-DOrcia.dx6047918)[Hotels in Val d'Orcia](https://expedia.co.uk/Val-DOrcia-Hotels.d6047918.Travel-Guide-Hotels)[Holiday Rentals in Val d'Orcia](https://expedia.co.uk/Val-DOrcia-Holiday-Rentals.d6047918.Travel-Guide-HolidayRentals)[Flights to Val d'Orcia](https://expedia.co.uk/Cheap-Flights-To-Val-DOrcia.d6047918.Travel-Guide-Flights)[Val d'Orcia Car Hire](https://expedia.co.uk/Compare-Cheap-Car-Hire-In-Val-DOrcia.d6047918.Car-Hire-Guide)[Val d'Orcia Holidays](https://expedia.co.uk/Val-DOrcia.d6047918.Holidays-City-Breaks) ![Cathedral of Pienza showing heritage architecture](https://a.travel-assets.com/findyours-php/viewfinder/images/res70/157000/157954-Pienza.jpg?impolicy=fcrop&w=1200&h=500&q=medium) # Compare and book 5 Star hotels in Val d'Orcia, Tuscany - ![](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__price_find.svg) ### Change your mind Book hotels with free cancellation - ![](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__deals.svg) ### Treat yourself Save instantly and earn perks with One Key [Learn about One Key](https://www.expedia.co.uk/welcome-one-key) - ![](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__bed.svg) ### Be picky Search almost a million properties worldwide ## Check availability on Val d'Orcia 5 Star Hotels Tonight [2 Nov - 3 Nov](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2025-11-02&endDate=2025-11-03&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) Tomorrow [3 Nov - 4 Nov](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2025-11-03&endDate=2025-11-04&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) Next weekend [7 Nov - 9 Nov](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2025-11-07&endDate=2025-11-09&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) In two weeks [14 Nov - 16 Nov](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2025-11-14&endDate=2025-11-16&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) ## Top Val d'Orcia 5 Star Hotels ![View from property](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/87359911.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Suite Terrace (UNESCO view) | Terrace/patio](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/00d01fce.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Aerial view](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/56195c00.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Exterior detail](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/5f1c53d5.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Castello di Velona Resort Thermal SPA & Winery Montalcino 9.0/10 Wonderful (335) "Absolutely stunning property and an exceptional staff. " ![United States](https://a.travel-assets.com/egds/marks/flags/us.svg) David [](https://www.expedia.co.uk/Montalcino-Hotels-Castello-Di-Velona-Resort-The-Leading-Hotels-Of-The-World.h1037832.Hotel-Information) ![2 outdoor pools, open 8:30 AM to 6:30 PM, pool umbrellas, pool loungers](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/9ace3d4a.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![2 restaurants, breakfast, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/8826686a.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![2 restaurants, breakfast, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/7c5ee645.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Villa (Sant'Anna) | Premium bedding, down duvets, minibar, in-room safe](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/8e24bdea.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Rosewood Castiglion del Bosco Montalcino 10/10 Exceptional (67) "Definitely the best property in Tuscany.. People, food, amenities, the property itself - all perfect !" ![United Kingdom](https://a.travel-assets.com/egds/marks/flags/uk.svg) IOSEFIN £1,023 includes taxes & fees 16 Nov - 17 Nov [](https://www.expedia.co.uk/Montalcino-Hotels-Rosewood-Castiglion-Del-Bosco.h2173539.Hotel-Information) ![2 restaurants, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/89af6209.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![2 restaurants, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/554821c2.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Junior Suite | View from room](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/cda9c123.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Aerial view](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/09b92259.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Castello Banfi - Il Borgo Montalcino 10/10 Exceptional (123) "Great property and excellent dining options. I had to cut one star due reception " ![United States](https://a.travel-assets.com/egds/marks/flags/us.svg) Virendra £733 includes taxes & fees 5 Nov - 6 Nov [](https://www.expedia.co.uk/Montalcino-Hotels-Castello-Banfi-Il-Borgo.h4774015.Hotel-Information) ![Lunch and dinner served, local cuisine](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/0969c7fd.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Property amenity](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/6331f08f.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Lunch and dinner served, local cuisine](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/7da4b709.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Front of property](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/eac33ee9.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### La Posta Hotel & Thermal Spa San Quirico d'Orcia 9.8/10 Exceptional (69) "Beautiful property. We were able to extend a late check out as we did not want to leave but had plans in Roma. " ![United States](https://a.travel-assets.com/egds/marks/flags/us.svg) Jose £355 includes taxes & fees 25 Nov - 26 Nov [](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-Albergo-Posta-Marcucci.h19361241.Hotel-Information) ![Exterior](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/f48ee625.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Games room](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/f66b0061.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Exterior](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/7b526713.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Front of property](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/85394594.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### ADLER Spa Resort Thermae San Quirico d'Orcia 9.4/10 Exceptional (68) "ADLER Spa Resort Thermae is exceptional. From the warm welcome to the first-class property, everything exceeded expectations. Meals were outstanding, and as someone gluten free, I appreciated the wide range of safe, clearly marked options. The spa and thermal pool are incredible, and the 50km guided e-bike ride through the countryside was unforgettable. The daily sound bath was a unique highlight, and a rainy afternoon wine tasting and lunch turned into a cozy, memorable experience. Ask for... ![Canada](https://a.travel-assets.com/egds/marks/flags/ca.svg) Jim [](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-ADLER-Spa-Resort-Thermae.h2232499.Hotel-Information) ![](https://a.travel-assets.com/pricing-claim/sparkle_dark.svg) Save an average of 15% on thousands of hotels when you're signed in [Sign in](https://expedia.co.uk/user/signin?ckoflag=0&uurl=e3id%3Dredr%26rurl%3D%2F5Star-Val-DOrcia-Hotels.s50-0-d6047918.Travel-Guide-Filter-Hotels)[Sign up, it's free](https://expedia.co.uk/signup?enable_registration=true&+=&uurl=e3id%3Dredr%26rurl%3D%2F5Star-Val-DOrcia-Hotels.s50-0-d6047918.Travel-Guide-Filter-Hotels) ## Explore similar 4-star hotels Many 4-star hotels have the same amenities as 5-star hotels. See all 4-star hotels in Val d'Orcia. ![Hotel Relais II Chiostro di Pienza](https://images.trvl-media.com/lodging/1000000/900000/893100/893017/ef61d192_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Relais II Chiostro di Pienza Corso Rossellino 26, Pienza, SI [Get rates](https://expedia.co.uk/Hotel-Search?startDate=16%2F11%2F2025&endDate=17%2F11%2F2025&selected=893017&PinnedHotelID=893017&HadPinnedHotel=true®ionId=6047918) 8.6/10 Excellent! (606 reviews) [](https://expedia.co.uk/Pienza-Hotels-Hotel-Relais-II-Chiostro-Di-Pienza.h893017.Hotel-Information) ![Hotel Corsignano](https://images.trvl-media.com/lodging/3000000/2530000/2525700/2525690/e0c5b2be_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Corsignano Via Della Madonnina 11, Pienza, SI £122 20 Nov - 21 Nov includes taxes & fees 9.4/10 Exceptional! (322 reviews) [](https://expedia.co.uk/Pienza-Hotels-Hotel-Corsignano.h2525690.Hotel-Information) ![ Hotel Palazzo del Capitano Wellness & Relais - Luxury Borgo Capitano Collection](https://images.trvl-media.com/lodging/2000000/1120000/1111500/1111483/fbe5451e_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Palazzo del Capitano Wellness & Relais - Luxury Borgo Capitano Collection Via Poliziano 18, Bagno Vignoni, San Quirico d'Orcia, SI £152 3 Nov - 4 Nov includes taxes & fees 9.2/10 Wonderful! (219 reviews) [](https://expedia.co.uk/San-Quirico-DOrcia-Hotels-Hotel-Palazzo-Del-Capitano-Wellness-Relais-Historic-Luxury-Capitano-Collection.h1111483.Hotel-Information) Still don't see what you're looking for? [See all properties in Val d'Orcia.](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=03%2F11%2F2025&endDate=04%2F11%2F2025®ionId=6047918&star=50) You can also use these popular filters to refine your search. [Pool](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=03%2F11%2F2025&endDate=04%2F11%2F2025®ionId=6047918&star=50&star=50&amenities=POOL)[Spa](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=03%2F11%2F2025&endDate=04%2F11%2F2025®ionId=6047918&star=50&star=50&amenities=SPA_ON_SITE)[Hot tub](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=03%2F11%2F2025&endDate=04%2F11%2F2025®ionId=6047918&star=50&star=50&amenities=HOT_TUB)[Breakfast included](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=03%2F11%2F2025&endDate=04%2F11%2F2025®ionId=6047918&star=50&star=50&amenities=FREE_BREAKFAST)[Waterpark](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=03%2F11%2F2025&endDate=04%2F11%2F2025®ionId=6047918&star=50&star=50&amenities=WATER_PARK) Lowest nightly price found within the past 24 hours based on a 1 night stay for 2 adults. Prices and availability subject to change. Additional terms may apply. ## Learn more about Val d'Orcia Wineries, pristine countryside and sights from Horti Leonini to Abbazia di Sant'Antimo—discover it all in Val d'Orcia. [See all hotels in Val d'Orcia](https://www.expedia.co.uk/Hotel-Search?startDate=2025-11-16&endDate=2025-11-17&adults=2®ionId=6047918) ![Scenic Tuscany landscape panorama with rolling hills and harvest fields in golden morning light, Val d'Orcia, Italy.](https://images.trvl-media.com/place/6047918/77cb6ee7-1415-4b8a-a03c-1f20e4ced8af.jpg?impolicy=fcrop&w=900&h=337&p=1&q=high) ## Top Val d'Orcia Hotel Reviews ![Castello di Velona Resort Thermal SPA & Winery](//images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/87359911_y.jpg) ### Castello di Velona Resort Thermal SPA & Winery 10/10 Excellent "Everything was 5 star. It’s like living in a castle in the sky with hot thermal pools everywhere and amazing food. We loved our outdoor patio with the sunset view of the panorama." [](https://expedia.co.uk/Montalcino-Hotels-Castello-Di-Velona-Resort-The-Leading-Hotels-Of-The-World.h1037832.Hotel-Information) ![Rosewood Castiglion del Bosco](//images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/9ace3d4a_y.jpg) ### Rosewood Castiglion del Bosco 10/10 Excellent "Beautiful property and great service. Was a little disappointed they charge double the price for wine they make in their back yard then I pay here in Montreal." [](https://expedia.co.uk/Montalcino-Hotels-Rosewood-Castiglion-Del-Bosco.h2173539.Hotel-Information) ## Find out more about Val d'Orcia ## Frequently asked questions ### What are the best 5-star hotels in Val d'Orcia? > If you're looking for a 5-star experience, [ADLER Spa Resort Thermae](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-ADLER-Spa-Resort-Thermae.h2232499.Hotel-Information) offers one of the best of them based on Expedia traveller reviews. Stay at this Val d'Orcia getaway and you'll get amazing guest services, premium guest rooms and top-notch facilities. ### How much does it cost to stay in a 5-star hotel in Val d'Orcia? > How much you pay for a 5-star hotel in Val d'Orcia can vary according to when you want to travel and how long you plan to be away, among a number of factors. Take advantage of our price per night filter and other search tools to find the best deal on a luxurious getaway. > > > > - Search for the lowest price per night from £122 ### What makes a hotel 5 stars in Val d'Orcia? > From high-end restaurants and all-day gyms to swimming pools and luxury bedding, the 5-star experience in Val d'Orcia is all about relaxation and luxury. But it requires more than just top-notch amenities to earn a 5-star rating. 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