Title: The 10 Best 5 Star Hotels in Val d'Orcia - 2026 Updated Prices | Expedia.co.uk [Val d'Orcia Travel Guide](https://expedia.co.uk/Val-DOrcia.dx6047918)[Hotels in Val d'Orcia](https://expedia.co.uk/Val-DOrcia-Hotels.d6047918.Travel-Guide-Hotels)[Holiday Rentals in Val d'Orcia](https://expedia.co.uk/Val-DOrcia-Holiday-Rentals.d6047918.Travel-Guide-HolidayRentals)[Flights to Val d'Orcia](https://expedia.co.uk/Cheap-Flights-To-Val-DOrcia.d6047918.Travel-Guide-Flights)[Things to do in Val d'Orcia](https://expedia.co.uk/Things-To-Do-In-Val-DOrcia.d6047918.Travel-Guide-Activities)[Val d'Orcia Car Hire](https://expedia.co.uk/Compare-Cheap-Car-Hire-In-Val-DOrcia.d6047918.Car-Hire-Guide)[Val d'Orcia Holidays](https://expedia.co.uk/Val-DOrcia.d6047918.Holidays-City-Breaks) ![Scenic Tuscany landscape panorama with rolling hills and harvest fields in golden morning light, Val d'Orcia, Italy.](https://images.trvl-media.com/place/6047918/77cb6ee7-1415-4b8a-a03c-1f20e4ced8af.jpg?impolicy=fcrop&w=1200&h=500&q=medium) ![](https://images.trvl-media.com/place/6047918/77cb6ee7-1415-4b8a-a03c-1f20e4ced8af.jpg?impolicy=fcrop&w=1200&h=500&q=medium) - ![](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__price_find.svg) ### Change your mind Book hotels with free cancellation - ![](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__deals.svg) ### Treat yourself Save instantly and earn perks with One Key [Learn about One Key](https://www.expedia.co.uk/welcome-one-key) - ![](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__bed.svg) ### Be picky Search almost a million properties worldwide ## Check availability on Val d'Orcia 5 Star Hotels Tonight [5 Feb - 6 Feb](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2026-02-05&endDate=2026-02-06&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) Tomorrow [6 Feb - 7 Feb](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2026-02-06&endDate=2026-02-07&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) This weekend [6 Feb - 8 Feb](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2026-02-06&endDate=2026-02-08&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) Next weekend [13 Feb - 15 Feb](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2026-02-13&endDate=2026-02-15&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) ## Our top choices for Val d'Orcia 5-star hotels ![Villa (Agresto) | Living area | LCD TV, pay films](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/fd17fc16.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![2 restaurants, breakfast, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/7c5ee645.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Villa (Stabbi) | View from room](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/c373f952.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Building design](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/576c77ca.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Castiglion del Bosco, A Rosewood Hotel [](https://www.expedia.co.uk/Montalcino-Hotels-Rosewood-Castiglion-Del-Bosco.h2173539.Hotel-Information) Montalcino 10/10 Exceptional (73 reviews) "Wonderful stay " ![United States](https://a.travel-assets.com/egds/marks/flags/us.svg) Talib [](https://www.expedia.co.uk/Montalcino-Hotels-Rosewood-Castiglion-Del-Bosco.h2173539.Hotel-Information) ![View from property](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/87359911.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Vineyard](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/163b0d09.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Suite Terrace (UNESCO view) | Living area | 50-inch LCD TV with digital channels, TV](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/9be56e31.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Exterior detail](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/5f1c53d5.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Castello di Velona Resort Thermal SPA & Winery [](https://www.expedia.co.uk/Montalcino-Hotels-Castello-Di-Velona-Resort-The-Leading-Hotels-Of-The-World.h1037832.Hotel-Information) Montalcino 9.0/10 Wonderful (341 reviews) "The property was exquisite. The view spectacular and the staff top notch. The indoor and outdoor thermal pools and sauna made our stay very relaxing. The buffet breakfast was amazing." ![United States](https://a.travel-assets.com/egds/marks/flags/us.svg) Jose [](https://www.expedia.co.uk/Montalcino-Hotels-Castello-Di-Velona-Resort-The-Leading-Hotels-Of-The-World.h1037832.Hotel-Information) ![Junior Suite | View from room](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/cda9c123.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Courtyard](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/4bbcb08d.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Aerial view](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/91a951f0.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![2 restaurants, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/9b5cebd1.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Castello Banfi - Il Borgo - Relais et Chateaux [](https://www.expedia.co.uk/Montalcino-Hotels-Castello-Banfi-Il-Borgo.h4774015.Hotel-Information) Montalcino 10/10 Exceptional (126 reviews) "The setting, scenery and hotel were 5 star plus!" ![United States](https://a.travel-assets.com/egds/marks/flags/us.svg) Diana [](https://www.expedia.co.uk/Montalcino-Hotels-Castello-Banfi-Il-Borgo.h4774015.Hotel-Information) ![Indoor pool, 2 outdoor pools](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/a05f633e.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Poolside bar](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/8f59420f.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Lunch and dinner served, local cuisine](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/76a8c1ef.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Sauna, hot tub, steam room, hot springs/mineral springs](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/23d1a976.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### La Posta Hotel & Thermal Spa [](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-Albergo-Posta-Marcucci.h19361241.Hotel-Information) San Quirico d'Orcia 9.6/10 Exceptional (70 reviews) "Enjoyed our stay to the fullest!" ![United States](https://a.travel-assets.com/egds/marks/flags/us.svg) Anna £395 includes taxes & fees 8 Mar - 9 Mar [](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-Albergo-Posta-Marcucci.h19361241.Hotel-Information) ![Indoor pool, 2 outdoor pools, pool loungers](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/2d975158.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Valley view](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/71fbc9d0.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Couples treatment room(s), sauna, hot tub, steam room](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/9d0831a5.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Exterior](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/7b526713.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### ADLER Spa Resort Thermae [](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-ADLER-Spa-Resort-Thermae.h2232499.Hotel-Information) San Quirico d'Orcia 9.4/10 Exceptional (68 reviews) "Wonderful stay in Tuscany - marvellous staff and great food." ![Germany](https://a.travel-assets.com/egds/marks/flags/de.svg) Anonymous traveller [](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-ADLER-Spa-Resort-Thermae.h2232499.Hotel-Information) ![](https://a.travel-assets.com/pricing-claim/sparkle_dark.svg) Save an average of 15% on thousands of hotels when you're signed in [Sign in ](https://expedia.co.uk/user/signin?ckoflag=0&uurl=e3id%3Dredr%26rurl%3D%2F5Star-Val-DOrcia-Hotels.s50-0-d6047918.Travel-Guide-Filter-Hotels)[ Sign up, it's free ](https://expedia.co.uk/signup?enable_registration=true&+=&uurl=e3id%3Dredr%26rurl%3D%2F5Star-Val-DOrcia-Hotels.s50-0-d6047918.Travel-Guide-Filter-Hotels) ## Explore similar 4-star hotels Many 4-star hotels have the same amenities as 5-star hotels. See all 4-star hotels in Val d'Orcia. ![Hotel Relais II Chiostro di Pienza](https://images.trvl-media.com/lodging/1000000/900000/893100/893017/ef61d192_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Relais II Chiostro di Pienza Corso Rossellino 26 Pienza SI [Get rates](https://expedia.co.uk/Hotel-Search?startDate=19%2F02%2F2026&endDate=20%2F02%2F2026&selected=893017&PinnedHotelID=893017&HadPinnedHotel=true®ionId=6047918) 8.6/10 Excellent! (616 reviews) [](https://expedia.co.uk/Pienza-Hotels-Hotel-Relais-II-Chiostro-Di-Pienza.h893017.Hotel-Information) ![Hotel Corsignano](https://images.trvl-media.com/lodging/3000000/2530000/2525700/2525690/e0c5b2be_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Corsignano Via Della Madonnina 11 Pienza SI £99 5 Mar - 6 Mar includes taxes & fees 9.4/10 Exceptional! (328 reviews) [](https://expedia.co.uk/Pienza-Hotels-Hotel-Corsignano.h2525690.Hotel-Information) ![ Hotel Palazzo del Capitano Wellness & Relais - Luxury Borgo Capitano Collection](https://images.trvl-media.com/lodging/2000000/1120000/1111500/1111483/fbe5451e_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Palazzo del Capitano Wellness & Relais - Luxury Borgo Capitano Collection Via Poliziano 18 San Quirico d'Orcia SI £140 8 Feb - 9 Feb includes taxes & fees 9.2/10 Wonderful! (220 reviews) [](https://expedia.co.uk/San-Quirico-DOrcia-Hotels-Hotel-Palazzo-Del-Capitano-Wellness-Relais-Historic-Luxury-Capitano-Collection.h1111483.Hotel-Information) Still don't see what you're looking for? [See all properties in Val d'Orcia.](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=06%2F02%2F2026&endDate=07%2F02%2F2026®ionId=6047918&star=50) You can also use these popular filters to refine your search. [Pool](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=06%2F02%2F2026&endDate=07%2F02%2F2026®ionId=6047918&star=50&star=50&amenities=POOL)[Spa](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=06%2F02%2F2026&endDate=07%2F02%2F2026®ionId=6047918&star=50&star=50&amenities=SPA_ON_SITE)[Hot tub](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=06%2F02%2F2026&endDate=07%2F02%2F2026®ionId=6047918&star=50&star=50&amenities=HOT_TUB)[Breakfast included](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=06%2F02%2F2026&endDate=07%2F02%2F2026®ionId=6047918&star=50&star=50&amenities=FREE_BREAKFAST)[Waterpark](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=06%2F02%2F2026&endDate=07%2F02%2F2026®ionId=6047918&star=50&star=50&amenities=WATER_PARK) Lowest nightly price found within the past 24 hours based on a 1 night stay for 2 adults. Prices and availability subject to change. Additional terms may apply. ## Learn more about Val d'Orcia Wineries, pristine countryside and sights from Piazza delle Sorgenti to Horti Leonini—discover it all in Val d'Orcia. [See all hotels in Val d'Orcia](https://www.expedia.co.uk/Hotel-Search?startDate=2026-02-19&endDate=2026-02-20&adults=2®ionId=6047918) ![Scenic Tuscany landscape panorama with rolling hills and harvest fields in golden morning light, Val d'Orcia, Italy.](https://images.trvl-media.com/place/6047918/77cb6ee7-1415-4b8a-a03c-1f20e4ced8af.jpg?impolicy=fcrop&w=900&h=337&p=1&q=high) ## Top Val d'Orcia Hotel Reviews ![Rosewood Castiglion del Bosco](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/9ace3d4a_y.jpg) ### Rosewood Castiglion del Bosco 10/10 Excellent "Wonderful stay " [](https://expedia.co.uk/Montalcino-Hotels-Rosewood-Castiglion-Del-Bosco.h2173539.Hotel-Information) ![Castello di Velona Resort Thermal SPA & Winery](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/87359911_y.jpg) ### Castello di Velona Resort Thermal SPA & Winery 10/10 Excellent "The property was exquisite. The view spectacular and the staff top notch. The indoor and outdoor thermal pools and sauna made our stay very relaxing. The buffet breakfast was amazing." [](https://expedia.co.uk/Montalcino-Hotels-Castello-Di-Velona-Resort-The-Leading-Hotels-Of-The-World.h1037832.Hotel-Information) ![ADLER Spa Resort Thermae](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/f48ee625_y.jpg) ### ADLER Spa Resort Thermae 10/10 Excellent "ADLER Spa Resort Thermae is exceptional. From the warm welcome to the first-class property, everything exceeded expectations. Meals were outstanding, and as someone gluten free, I appreciated the wide range of safe, clearly marked options. The spa and thermal pool are incredible, and the 50km guided e-bike ride through the countryside was unforgettable. The daily sound bath was a unique highlight, and a rainy afternoon wine tasting and lunch turned into a cozy, memorable experience. Ask for Julia’s tour—you’ll come away with a whole new appreciation for organic winemaking. Our room was spacious, comfortable, and had a balcony overlooking the beautiful grounds. We enjoyed it so much we extended our stay by two extra days. Can’t wait to return." [](https://expedia.co.uk/San-Quirico-DOrcia-Hotels-ADLER-Spa-Resort-Thermae.h2232499.Hotel-Information) ## Find out more about Val d'Orcia ## Frequently asked questions ### What are the best 5-star hotels in Val d'Orcia? ### How much does it cost to stay in a 5-star hotel in Val d'Orcia? > - Search for the lowest price per night from £99 ### What makes a hotel 5 stars in Val d'Orcia? ## Explore a world of travel with Expedia - Accommodation - Flights - Packages - Cars - Holiday Homes - Other - More ways to book - [2 Star Hotels in Maremma ](https://www.expedia.co.uk/2Star-Maremma-Hotels.s20-0-d553248634855578977.Travel-Guide-Filter-Hotels) - [2 Star Hotels in Poggi del Sasso ](https://www.expedia.co.uk/2Star-Poggi-Del-Sasso-Hotels.s20-0-d6056445.Travel-Guide-Filter-Hotels) - [3 Star Hotels in Cortona ](https://www.expedia.co.uk/3Star-Cortona-Hotels.s30-0-d601360.Travel-Guide-Filter-Hotels) - [3 Star Hotels in Crete Senesi ](https://www.expedia.co.uk/3Star-Crete-Senesi-Hotels.s30-0-d6342453.Travel-Guide-Filter-Hotels) - 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