Title: The 10 Best 5 Star Hotels in Val d'Orcia - 2025 Updated Prices | Expedia.co.uk [Val d'Orcia Travel Guide](https://expedia.co.uk/Val-DOrcia.dx6047918)[Hotels in Val d'Orcia](https://expedia.co.uk/Val-DOrcia-Hotels.d6047918.Travel-Guide-Hotels)[Holiday Rentals in Val d'Orcia](https://expedia.co.uk/Val-DOrcia-Holiday-Rentals.d6047918.Travel-Guide-HolidayRentals)[Flights to Val d'Orcia](https://expedia.co.uk/Cheap-Flights-To-Val-DOrcia.d6047918.Travel-Guide-Flights)[Val d'Orcia Car Hire](https://expedia.co.uk/Compare-Cheap-Car-Hire-In-Val-DOrcia.d6047918.Car-Hire-Guide)[Val d'Orcia Holidays](https://expedia.co.uk/Val-DOrcia.d6047918.Holidays-City-Breaks) ![Cathedral of Pienza showing heritage architecture](https://a.travel-assets.com/findyours-php/viewfinder/images/res70/157000/157954-Pienza.jpg?impolicy=fcrop&w=1200&h=500&q=medium) # Compare and book 5 Star hotels in Val d'Orcia, Tuscany ![price find illustration](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__price_find.svg) ### Change your mind Book hotels with free cancellation ![deals illustration](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__deals.svg) ### Treat yourself Save instantly and earn perks with One Key [Learn about One Key](https://www.expedia.co.uk/welcome-one-key) ![bed illustration](https://a.travel-assets.com/travel-assets-manager/pictogram-bex/light__bed.svg) ### Be picky Search almost a million properties worldwide ## Check availability on Val d'Orcia 5 Star Hotels Tonight [18 Sept - 19 Sept](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2025-09-18&endDate=2025-09-19&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) Tomorrow [19 Sept - 20 Sept](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2025-09-19&endDate=2025-09-20&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) This weekend [19 Sept - 21 Sept](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2025-09-19&endDate=2025-09-21&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) Next weekend [26 Sept - 28 Sept](https://www.expedia.co.uk/Hotel-Search?regionId=6047918&startDate=2025-09-26&endDate=2025-09-28&adults=2&star=50&rfrr=TG.LP.CheckPrices.Hotel&openPlayBack=true) ## Top Val d'Orcia 5 Star Hotels ![View from property](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/87359911.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Suite Terrace (UNESCO view) | Living area | 50-inch LCD TV with digital channels, TV](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/9be56e31.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Suite Terrace (UNESCO view) | Terrace/patio](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/00d01fce.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Aerial view](https://images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/56195c00.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Castello di Velona Resort Thermal SPA & Winery Montalcino 8.8/10 Excellent (333) "Absolutely stunning property and an exceptional staff. " £622 includes taxes & fees 7 Oct - 8 Oct [](https://www.expedia.co.uk/Montalcino-Hotels-Castello-Di-Velona-Resort-The-Leading-Hotels-Of-The-World.h1037832.Hotel-Information) ![2 outdoor pools, open 8:30 AM to 6:30 PM, pool umbrellas, pool loungers](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/9ace3d4a.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Villa (Sant'Anna) | Premium bedding, down duvets, minibar, in-room safe](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/8e24bdea.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![2 restaurants, breakfast, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/7c5ee645.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![2 restaurants, breakfast, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/8826686a.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Rosewood Castiglion del Bosco Montalcino 10/10 Exceptional (65) "Definitely the best property in Tuscany.. People, food, amenities, the property itself - all perfect !" £1,593 includes taxes & fees 10 Oct - 11 Oct [](https://www.expedia.co.uk/Montalcino-Hotels-Rosewood-Castiglion-Del-Bosco.h2173539.Hotel-Information) ![Lunch and dinner served, local cuisine](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/0969c7fd.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Front of property](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/eac33ee9.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Lunch and dinner served, local cuisine](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/7da4b709.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Property amenity](https://images.trvl-media.com/lodging/20000000/19370000/19361300/19361241/6331f08f.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### La Posta Hotel & Thermal Spa San Quirico d'Orcia 9.8/10 Exceptional (65) "Peaceful location with stunning view and well trained staff It was a perfect family vacation My only mistake is not having the time to stay a full week Would come back with our child when they are older " £344 includes taxes & fees 19 Oct - 20 Oct [](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-Albergo-Posta-Marcucci.h19361241.Hotel-Information) ![2 restaurants, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/89af6209.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Aerial view](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/91a951f0.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Junior Suite | View from room](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/cda9c123.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![2 restaurants, lunch, dinner served; Italian cuisine ](https://images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/554821c2.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### Castello Banfi - Il Borgo Montalcino 10/10 Exceptional (119) "Great property and excellent dining options. I had to cut one star due reception " £841 includes taxes & fees 19 Oct - 20 Oct [](https://www.expedia.co.uk/Montalcino-Hotels-Castello-Banfi-Il-Borgo.h4774015.Hotel-Information) ![Exterior](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/f48ee625.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Exterior](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/7b526713.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Games room](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/f0062d86.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ![Front of property](https://images.trvl-media.com/lodging/3000000/2240000/2232500/2232499/85394594.jpg?impolicy=fcrop&w=357&h=201&p=1&q=medium) ### ADLER Spa Resort Thermae San Quirico d'Orcia 9.4/10 Exceptional (66) "ADLER Spa Resort Thermae is exceptional. From the warm welcome to the first-class property, everything exceeded expectations. Meals were outstanding, and as someone gluten free, I appreciated the wide range of safe, clearly marked options. The spa and thermal pool are incredible, and the 50km guided e-bike ride through the countryside was unforgettable. The daily sound bath was a unique highlight, and a rainy afternoon wine tasting and lunch turned into a cozy, memorable experience. Ask for... £605 includes taxes & fees 2 Oct - 3 Oct [](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-ADLER-Spa-Resort-Thermae.h2232499.Hotel-Information) ![](https://a.travel-assets.com/pricing-claim/sparkle_dark.svg) Save an average of 15% on thousands of hotels when you're signed in [Sign in](https://expedia.co.uk/user/signin?ckoflag=0&uurl=e3id%3Dredr%26rurl%3D%2F5Star-Val-DOrcia-Hotels.s50-0-d6047918.Travel-Guide-Filter-Hotels)[Sign up, it's free](https://expedia.co.uk/signup?enable_registration=true&+=&uurl=e3id%3Dredr%26rurl%3D%2F5Star-Val-DOrcia-Hotels.s50-0-d6047918.Travel-Guide-Filter-Hotels) ## Explore similar 4-star hotels Many 4-star hotels have the same amenities as 5-star hotels. See all 4-star hotels in Val d'Orcia. ![Hotel Relais II Chiostro di Pienza](https://images.trvl-media.com/lodging/1000000/900000/893100/893017/ef61d192_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Relais II Chiostro di Pienza Corso Rossellino 26, Pienza, SI [Get rates](https://expedia.co.uk/Hotel-Search?startDate=02%2F10%2F2025&endDate=03%2F10%2F2025&selected=893017&PinnedHotelID=893017&HadPinnedHotel=true®ionId=6047918) 8.6/10 Excellent! (593 reviews) [](https://expedia.co.uk/Pienza-Hotels-Hotel-Relais-II-Chiostro-Di-Pienza.h893017.Hotel-Information) ![Hotel Corsignano](https://images.trvl-media.com/lodging/3000000/2530000/2525700/2525690/e0c5b2be_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Corsignano Via Della Madonnina 11, Pienza, SI [Get rates](https://expedia.co.uk/Hotel-Search?startDate=02%2F10%2F2025&endDate=03%2F10%2F2025&selected=2525690&PinnedHotelID=2525690&HadPinnedHotel=true®ionId=6047918) 9.4/10 Exceptional! (309 reviews) [](https://expedia.co.uk/Pienza-Hotels-Hotel-Corsignano.h2525690.Hotel-Information) ![ Hotel Palazzo del Capitano Wellness & Relais - Luxury Borgo Capitano Collection](https://images.trvl-media.com/lodging/2000000/1120000/1111500/1111483/fbe5451e_y.jpg?impolicy=resizecrop&rw=402&ra=fit) ### Hotel Palazzo del Capitano Wellness & Relais - Luxury Borgo Capitano Collection Via Poliziano 18, Bagno Vignoni, San Quirico d'Orcia, SI £197 22 Sept - 23 Sept includes taxes & fees 9.2/10 Wonderful! (216 reviews) [](https://expedia.co.uk/San-Quirico-DOrcia-Hotels-Hotel-Palazzo-Del-Capitano-Wellness-Relais-Historic-Luxury-Capitano-Collection.h1111483.Hotel-Information) Still don't see what you're looking for? [See all properties in Val d'Orcia.](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=19%2F09%2F2025&endDate=20%2F09%2F2025®ionId=6047918&star=50) You can also use these popular filters to refine your search. [Pool](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=19%2F09%2F2025&endDate=20%2F09%2F2025®ionId=6047918&star=50&star=50&amenities=POOL)[Spa](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=19%2F09%2F2025&endDate=20%2F09%2F2025®ionId=6047918&star=50&star=50&amenities=SPA_ON_SITE)[Hot tub](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=19%2F09%2F2025&endDate=20%2F09%2F2025®ionId=6047918&star=50&star=50&amenities=HOT_TUB)[Breakfast included](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=19%2F09%2F2025&endDate=20%2F09%2F2025®ionId=6047918&star=50&star=50&amenities=FREE_BREAKFAST)[Waterpark](https://expedia.co.uk/Hotel-Search?rfrrid=TG.LP.Hotels.Hotel&startDate=19%2F09%2F2025&endDate=20%2F09%2F2025®ionId=6047918&star=50&star=50&amenities=WATER_PARK) Lowest nightly price found within the past 24 hours based on a 1 night stay for 2 adults. Prices and availability subject to change. Additional terms may apply. ## Learn more about Val d'Orcia Wineries, pristine countryside and sights from Horti Leonini to Abbazia di Sant'Antimo—discover it all in Val d'Orcia. [See all hotels in Val d'Orcia](https://www.expedia.co.uk/Hotel-Search?startDate=2025-10-02&endDate=2025-10-03&adults=2®ionId=6047918) ![Cathedral of Pienza showing heritage architecture](https://a.travel-assets.com/findyours-php/viewfinder/images/res70/157000/157954-Pienza.jpg?impolicy=fcrop&w=900&h=506&p=1&q=high) ## Top Val d'Orcia Hotel Reviews ![Castello di Velona Resort Thermal SPA & Winery](//images.trvl-media.com/lodging/2000000/1040000/1037900/1037832/87359911_y.jpg) ### Castello di Velona Resort Thermal SPA & Winery 10/10 Excellent "Me and my wife stayed there for our honeymoon. We had an exceptional time. The service was exceptional. The pools and amenities were very nice. Great! Breakfast was just free. Located close to montel Chino and many great wineries. Specifically, we really enjoyed the wine tasting. The entire staff were great but here were some standouts , We were helped by Kristian who made us feel extremely welcomed and Morris who performed our wine tasting and he was an exceptional. Strong recommendation, great value." [](https://expedia.co.uk/Montalcino-Hotels-Castello-Di-Velona-Resort-The-Leading-Hotels-Of-The-World.h1037832.Hotel-Information) ![Castello Banfi - Il Borgo](//images.trvl-media.com/lodging/5000000/4780000/4774100/4774015/89af6209_y.jpg) ### Castello Banfi - Il Borgo 10/10 Excellent "Very peaceful " [](https://expedia.co.uk/Montalcino-Hotels-Castello-Banfi-Il-Borgo.h4774015.Hotel-Information) ![Rosewood Castiglion del Bosco](//images.trvl-media.com/lodging/3000000/2180000/2173600/2173539/9ace3d4a_y.jpg) ### Rosewood Castiglion del Bosco 10/10 Excellent "Beautiful property and great service. Was a little disappointed they charge double the price for wine they make in their back yard then I pay here in Montreal." [](https://expedia.co.uk/Montalcino-Hotels-Rosewood-Castiglion-Del-Bosco.h2173539.Hotel-Information) ## Find out more about Val d'Orcia ## Frequently asked questions ### What are the best 5-star hotels in Val d'Orcia? > If you're looking for a 5-star experience, [ADLER Spa Resort Thermae](https://www.expedia.co.uk/San-Quirico-DOrcia-Hotels-ADLER-Spa-Resort-Thermae.h2232499.Hotel-Information) offers one of the best of them based on Expedia traveller reviews. Stay at this Val d'Orcia getaway and you'll get amazing guest services, premium guest rooms and top-notch facilities. ### How much does it cost to stay in a 5-star hotel in Val d'Orcia? > How much you pay for a 5-star hotel in Val d'Orcia can vary according to when you want to travel and how long you plan to be away, among a number of factors. Take advantage of our price per night filter and other search tools to find the best deal on a luxurious getaway. > > > > - Search for the lowest price per night from £197 ### What makes a hotel 5 stars in Val d'Orcia? > From high-end restaurants and all-day gyms to swimming pools and luxury bedding, the 5-star experience in Val d'Orcia is all about relaxation and luxury. But it requires more than just top-notch amenities to earn a 5-star rating. 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