Yes, you can. After you collect your bags at Franz Josef Strauss Intl. Airport (MUC), you’ll find the rental car center located at the Rental Car Center, Terminalstraße Mitte - Munich Airport Center - Level 03. Choose from Hertz/Dollar/Thrifty, Avis/Budget or Sixt/Flizzr. Alamo/Enterprise/National and Europcar/Rent-A-Car/Global are other suppliers worth taking a look at.